A 2,3-Butanedione Protected Chiral Glycine Equivalent — A New Building Block for the Stereoselective Synthesis of Enantiopure N-Protected α-Amino Acids.
✍ Scribed by Darren J. Dixon; Christopher I. Harding; Steven V. Ley; D. Matthew G. Tilbrook
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 26 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
37 8C) and the mixture was filtered in a UltraFree MC 30 000 MWCO centrifugal filtration unit (Millipore) at 3500 g for 7 min at 37 8C. The concentration of free substrate in the filtrate was quantified by ICP-MS and the bound fraction was calculated as % bound ([total]-[free])/[total]. The proton T
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rearrangement of the corresponding acylazides to the amine (VI). -(BADORREY, R.; CATIVIELA, C.;