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Stereoselective Synthesis of the Lituarine Tricyclic Spiroacetal.

✍ Scribed by Jeremy Robertson; Paul Meo; Jonathan W. P. Dallimore; Bryan M. Doyle; Christophe Hoarau

Publisher
John Wiley and Sons
Year
2005
Weight
9 KB
Volume
36
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Radical mediated stereoselective synthes
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Stereoselective synthesis of chiral spiroacetals starting from enol-ester 1, derived from D-manno lactone, is described. The strategy involves 1,4-addition of a variety of alcohols to 1 in the presence of NBS to give Ξ±bromo acetals, which undergo a regio-and stereoselective radical cyclisation to gi

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