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Stereoselective synthesis of the functionalized spirocyclic core of aranorosin

โœ Scribed by Wipf, Peter; Kim, Yuntae

Book ID
118246186
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
651 KB
Volume
58
Category
Article
ISSN
0022-3263

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Stereoselective synthesis of the fully f
Stereoselective synthesis of the fully functionalized core fragment of terpentecin
โœ Taotao Ling; Fatima Rivas; Emmanuel A. Theodorakis ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 232 KB

A stereoselective synthesis of the core fragment 4 of terpentecin is presented. The five contiguous asymmetric centers of 4 were prepared from enone 8 via a sequence of steps highlighted by: oxygenation of the C6 center by epoxidation of enone 18, methylenation of the C8 carbonyl group of 20 by mean