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Stereoselective Synthesis of Oligo-α(2,8)-3-deoxy-D-manno-2-octulosonic Acid Derivatives.

✍ Scribed by Hiroshi Tanaka; Daisuke Takahashi; Takashi Takahashi

Publisher: John Wiley and Sons
Year: 2006
Weight: 8 KB
Volume: 37
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200618196

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📜 SIMILAR VOLUMES

Stereoselective Synthesis of Oligo-α(2,8

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Stereoselective Synthesis of Oligo-α(2,8

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Synthesis of 3-Deoxy-D-manno-2-octuloson

Synthesis of 3-Deoxy-D-manno-2-octulosonic Acid (KDO)

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ChemInform Abstract: Total Synthesis of

ChemInform Abstract: Total Synthesis of 3-Deoxy-D-manno-2-octulosonic Acid (KDO) and 2-Deoxy-β-KDO.

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A Silicon-Mediated Synthesis of 3-Deoxy-

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✍ Nico Bräuer; Andreas Kirschning; Ernst Schaumann 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 115 KB 👁 2 views

KDO (1) is synthesized in five steps, starting from 1,2-to the carbonate 9. Silicon-induced lactonization affords the lactone 10, which can be converted into NH 4 -KDO by anhydro-3,4:5,6-di-O-isopropylidene-D-mannitol ( 6). The epoxide 6, obtained from D-mannitol (2), reacts with lithiated standard