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Stereoselective Synthesis of Chiral Amino Allenes by Organocopper-Mediated anti-SN2′-Substitution Reaction of Chiral Ethynylaziridines

✍ Scribed by Hiroaki Ohno; Ayako Toda; Nobutaka Fujii; Yoshiji Takemoto; Tetsuaki Tanaka; Toshiro Ibuka

Book ID: 104202585
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 278 KB
Volume: 56
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(00)00136-8

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Synthesis of chiral amino allenes via an

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Synthesis of Chiral Amino Allenes via an Organocyanocuprate-Mediated Ring-Opening Reaction of Enantiopure Ethynylaziridines. -Enantiopure ethynylaziridines react with higher organocuprates in a completely stereoselective manner to yield the corresponding chiral amino allenes.

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Umpolung of Chiral 2-Ethynylaziridines:

Umpolung of Chiral 2-Ethynylaziridines: Indium(I)-Mediated Stereoselective Synthesis of Nonracemic 1,3-Amino Alcohols Bearing Three Chiral Centers, Catalyzed by Palladium(0)

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