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ChemInform Abstract: Synthesis of Chiral Amino Allenes via an Organocyanocuprate-Mediated Ring-Opening Reaction of Enantiopure Ethynylaziridines.

✍ Scribed by Hiroaki Ohno; Ayako Toda; Yoshihisa Miwa; Tooru Taga; Nobutaka Fujii; Toshiro Ibuka

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199916085

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✦ Synopsis

Synthesis of Chiral Amino Allenes via an Organocyanocuprate-Mediated Ring-Opening Reaction of Enantiopure Ethynylaziridines.

-Enantiopure ethynylaziridines react with higher organocuprates in a completely stereoselective manner to yield the corresponding chiral amino allenes.

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