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ChemInform Abstract: Stereoselective Synthesis of Chiral Amino Allenes by Organocopper-Mediated anti-SN2′-Substitution Reaction of Chiral Ethynylaziridines.

✍ Scribed by Hiroaki Ohno; Ayako Toda; Nobutaka Fujii; Yoshiji Takemoto; Tetsuaki Tanaka; Toshiro Ibuka

Publisher
John Wiley and Sons
Year
2001
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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Synthesis of Chiral Amino Allenes via an Organocyanocuprate-Mediated Ring-Opening Reaction of Enantiopure Ethynylaziridines. -Enantiopure ethynylaziridines react with higher organocuprates in a completely stereoselective manner to yield the corresponding chiral amino allenes.

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