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Stereoselective synthesis of basiliskamides A and B via Prins cyclisation

✍ Scribed by J.S. Yadav; P. Purushothama Rao; M. Sridhar Reddy; A.R. Prasad


Book ID
104095596
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
170 KB
Volume
49
Category
Article
ISSN
0040-4039

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✦ Synopsis


A stereoselective and convergent approach to basiliskamides A and B is achieved through our recently developed strategy for the construction of polyketide precursors via Prins cyclisation. The approach mainly relies upon reductive opening of 1-iodomethyl cyclic ethers, Mitsunobu inversion, Takai olefination and Stille coupling along with Prins cyclisation.


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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v