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Stereoselective Synthesis of Axially Chiral N−C Bonds in N -Aryl Indoles

✍ Scribed by Kamikawa, Ken; Kinoshita, Shunsuke; Matsuzaka, Hiroyuki; Uemura, Motokazu

Book ID
127384773
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
91 KB
Volume
8
Category
Article
ISSN
1523-7060

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ChemInform Abstract: Induction of Axiall
ChemInform Abstract: Induction of Axially Chiral N—C Bonds in N-Aryl Acridane and Related Complexes by Chromium Tricarbonyl Migration Reactions.
✍ Akiyoshi Mori; Shunsuke Kinoshita; Masaru Furusyo; Ken Kamikawa 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 27 KB 👁 2 views

## Abstract Axially chiral N—C bonds are obtained in products (II) by diastereoselective migration of Cr(CO)~3~ from the benzene ring in (I) to the acridane or phenoxazine system in (II).