ChemInform Abstract: Induction of Axially Chiral N—C Bonds in N-Aryl Acridane and Related Complexes by Chromium Tricarbonyl Migration Reactions.

✍ Scribed by Akiyoshi Mori; Shunsuke Kinoshita; Masaru Furusyo; Ken Kamikawa

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 27 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201106199

✦ Synopsis

Abstract

Axially chiral N—C bonds are obtained in products (II) by diastereoselective migration of Cr(CO)~3~ from the benzene ring in (I) to the acridane or phenoxazine system in (II).