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Stereoselective intramolecular addition of a grignard reagent to the terminal trimethylsilylethene moiety

✍ Scribed by Kiitiro Utimoto; Katsuharu Imi; Hiroshi Shiragami; Sadao Fujikura; Hitosi Nozaki

Publisher: Elsevier Science
Year: 1985
Tongue: French
Weight: 115 KB
Volume: 26
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)94789-0

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✦ Synopsis

Reaction of (E)-6-bromo-3-methyl-1-trimethylsilyl-1-hexene with magnesium produces corresponding Grignard reagent which intramolecularly adds to the silylethene moiety from the less hindered side affording a single stereoisomer.

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