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Stereochemistry of the addition of a grignard reagent to terpene ketones with seven-membered rings

✍ Scribed by É. N. Manukov; O. G. Vyglazov; V. A. Chuiko


Publisher
Springer
Year
1986
Tongue
English
Weight
321 KB
Volume
22
Category
Article
ISSN
0009-3130

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✍ C. Cardellicchio; V. Fiandanese; G. Marchese; L. Ronzini 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 227 KB

The sequential coupling reactions of Grignard reagents with S-phenyl carbonochloridothioate in the presence of nickel(I1) or' iron(II1) catalysts provides a very mild and straightforward route to symmetrical and unsymmetrical aliphatic and aromatic ketones.