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Stereoselective Insertion of Formamides into the C−Si Bond of Siliranes

✍ Scribed by Shaw, Jared T.; Woerpel, K. A.


Book ID
125899029
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
139 KB
Volume
62
Category
Article
ISSN
0022-3263

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Kinetic investigations on the insertion of metal-carbenoid intermediates into the Si-H bond have been carried out. A kinetic isotope effect of 1.5 was found and the plot of log kx/krt vs cr for the reaction of arylsilanes with EDA, gave a straight line with p =-0.31. It was thus concluded that the i