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Stereoselective Formation of Formal Exo Diels−Alder Adducts of Silyloxydienes and Allenecarboxylates

✍ Scribed by Jung, Michael E.; Nishimura, Nobuko


Book ID
126205208
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
114 KB
Volume
121
Category
Article
ISSN
0002-7863

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exo-Stereoselectivity in Diels-Alder Add
✍ Paul Müller; Gérald Bernardinelli; Jean Pfyffer; Domingo Rodriguez; Jean-Pierre 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 German ⚖ 359 KB

The 'exo'and 'endo'descriptors are used to designate the orientation of the cyclopropane ring in the transition states andin the products of the cycloaddition to furans. The use of these descriptors is extended, by analogy, to cycloadditions of cyclopropenes to open-chain dienes [3] [4]. Data were