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Exo-Selective Diels−Alder Reactions of Vinylazepines. Origin of Divergent Stereoselectivity in Diels−Alder Reactions of Vinylazepines, Vinylpiperideines, and Vinylcycloalkenes

✍ Scribed by Boren, Brant; Hirschi, Jennifer S.; Reibenspies, Joseph H.; Tallant, Matthew D.; Singleton, Daniel A.; Sulikowski, Gary A.

Book ID
127188514
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
150 KB
Volume
68
Category
Article
ISSN
0022-3263

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The high endo/exo product ratio in the Diels-Alder reaction of cyclopentadiene with methy2. vinyl! ketone in water does not reflect aggregation, but the ratio is affected by salts which change the hydrophobicity of the medium.