Endo−Exo and Facial Stereoselectivity in the Diels−Alder Reactions of 3-Substituted Cyclopropenes with Butadiene
✍ Scribed by Xidos, James D.; Gosse, Tammy L.; Burke, E. Diane; Poirier, Raymond A.; Burnell, D. Jean
- Book ID
- 126302295
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 155 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0002-7863
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Ab initio calcdations at the MP2/6-31G\*//HF/3-21G\* level have been carried out to study Eels-Alder reactions of 2-substituted-1,3-dienes with s u l h dioxide. The CH ... 0 electrostatic interaction detected in some of the transition structures located could be decisive in the control of the exo/en