## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
ChemInform Abstract: Endo—Exo and Facial Stereoselectivity in the Diels—Alder Reactions of 3-Substituted Cyclopropenes (I) with Butadiene.
✍ Scribed by James D. Xidos; Tammy L. Gosse; E. Diane Burke; Raymond A. Poirier; D. Jean Burnell
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 27 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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Ab initio calcdations at the MP2/6-31G\*//HF/3-21G\* level have been carried out to study Eels-Alder reactions of 2-substituted-1,3-dienes with s u l h dioxide. The CH ... 0 electrostatic interaction detected in some of the transition structures located could be decisive in the control of the exo/en
Geminal Bond Participation and Reactivities of Z-vs E-1-Substituted Butadienes in the Diels-Alder Reactions. -Analysis of the electronic structures of the transition states in Diels-Alder reactions of butadienes (I)-(VI) with ethylene discloses the significant participation of the geminal σ bonds at