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ChemInform Abstract: New Insights into the endo-exo Stereoselectivity of the Intramolecular Diels—Alder Reaction of 1,3,8-Nonatrienes.

✍ Scribed by Michael J. Lilly; Michael N. Paddon-Row; Michael S. Sherburn; Craig I. Turner

Publisher
John Wiley and Sons
Year
2001
Weight
28 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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Ab initio calcdations at the MP2/6-31G\*//HF/3-21G\* level have been carried out to study Eels-Alder reactions of 2-substituted-1,3-dienes with s u l h dioxide. The CH ... 0 electrostatic interaction detected in some of the transition structures located could be decisive in the control of the exo/en