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Stereoselective electrooxidation of a thiane to the corresponding thiane oxide

โœ Scribed by Makoto Kimura; Nobuo Kuriki; Morio Inaishi; Yasuhiko Sawaki

Book ID
104242418
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
214 KB
Volume
25
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

A remarkable difference in the conformat
A remarkable difference in the conformational preference of the so-bond in 1,3-di-thiane-1-oxides and 1,3-oxathiane-3-oxides.
โœ L. Van Acker; M. Anteunis ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

The sulfoxide group shows a lot of interesting stereochemical features (2). In thiane-l-oxide the axial conformation (62% of the mixture at -9OOC) is favored by 175 Cal/mole (2). Introduction of a 3,3-dimethyl grouping reverses this axial