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Stereoselective Access to Substituted [(E)- or (Z)-1-(Trifluoromethyl)allyl]amines

✍ Scribed by Guillaume Magueur; Benoit Crousse; Danièle Bonnet-Delpon

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
200 KB
Volume
2008
Category
Article
ISSN
1434-193X

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✦ Synopsis

Abstract

Hydrometallation reactions, for example, hydroboration and hydroalumination, on [1‐(trifluoromethyl)propargyl]amines lead stereoselectively to the corresponding [(Z)‐ and (E)‐1‐(trifluoromethyl)allyl]amines in good yields; (Z)‐ and (E)‐allylamines with a free amino group can be obtained in good yields and excellent enantioselectivities from the chiral propargylamines.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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