## Abstract Hydrometallation reactions, for example, hydroboration and hydroalumination, on [1β(trifluoromethyl)propargyl]amines lead stereoselectively to the corresponding [(__Z__)β and (__E__)β1β(trifluoromethyl)allyl]amines in good yields; (__Z__)β and (__E__)βallylamines with a free amino group
ChemInform Abstract: Stereoselective Access to Substituted [(E)- or (Z)-1-(Trifluoromethyl)allyl]amines.
β Scribed by Guillaume Magueur; Benoit Crousse; Daniele Bonnet-Delpon
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 57 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
Stereoselective Routes to E and Z Straight-Chain Primary Allylic Amines. -An efficient, general and versatile access to straight-chain primary (Z)-allylic amines (IX) from alk-2-yn-1-ols (I) is described involving catalytic reduction of (VIII). The corresponding (E)-allylic amines can be obtained b