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ChemInform Abstract: Stereoselective Routes to E and Z Straight-Chain Primary Allylic Amines.

✍ Scribed by B. TOMASSY; A. ZWIERZAK

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Stereoselective Routes to E and Z Straight-Chain Primary Allylic Amines.

-An efficient, general and versatile access to straight-chain primary (Z)-allylic amines (IX) from alk-2-yn-1-ols (I) is described involving catalytic reduction of (VIII). The corresponding (E)-allylic amines can be obtained by reduction of (I) with LiAlH 4 using a known protocol. -(TOMASSY, B.;

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