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Stereoselective [2,3]-wittig rearrangement of (1S,2R)-1-amino-indan-2-ol derived amide enolates

✍ Scribed by Michael H. Kress; Chunhua Yang; Nobuyoshi Yasuda; E.J.J. Grabowski

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
264 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

An efficient, diastereoselective [2,3]-Wittig rearrangement of~x-allyloxyamide enolates has been developed using (1S,2R)-l-amino-indan-2-ol as a chiral auxiliary. After auxiliary removal, the resultant optically active a-hydroxy acids have been transformed to functionalized amino acid derivatives.

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