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Stereoelectronic Substituent Effects

✍ Scribed by Henrik Helligsoe Jensen; Mikael Bols


Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES


Stereoelectronic Substituent Effects in
✍ Henrik HelligsΓΈ Jensen; Laila Lyngbye; Astrid Jensen; Mikael Bols πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 178 KB

From the pK a values of the conjugate acids of a large series of hydroxylated piperidines and hexahydropyridazines, a consistent difference in basicity was found between stereoisomers having an axial or equatorial hydroxyl (OH) group either b or g to the amine. Compounds with an equatorial OH group

Inductive substituent effects
✍ Vladimir I. Galkin πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 57 KB

A brief description and analysis of the history of and modern situation in the field of inductive effects, methods for its quantitative determination and prospects are presented, including a discussion of the underlying mechanism.