The aniline molecule is nonplanar, with its NH 2 group lying at an angle ฮธ of approximately 42 โข to the plane of the benzene ring. Substituents on the phenyl ring alter this out-of-plane angle as well as other molecular properties such as the ring bond lengths and angles, the barrier to inversion E
Substituent Effects on the Stereoelectronic and Chemical Properties of a Novel Phosphapalladacycle
โ Scribed by Joseph Kok-Peng Ng; Shuli Chen; Geok-Kheng Tan; Pak-Hing Leung
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 304 KB
- Volume
- 2007
- Category
- Article
- ISSN
- 1434-1948
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## Abstract ^13^C chemical shifts and ^31^P,^13^C coupling constants are reported for nine 1โhydroxyalkylphosphonic and two additional phosphonic acids. The ฮฑโsubstituentโinduced chemical shifts (ฮฑโSCS) of the phosphonate group were calculated and their nonโadditivity was observed. Good linear corr
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