Stereocontrolled synthesis of the C79–C96 fragment of symbiodinolide
✍ Scribed by Hiroyoshi Takamura; Junki Ando; Takashi Abe; Takeshi Murata; Isao Kadota; Daisuke Uemura
- Book ID
- 108285032
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- French
- Weight
- 305 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Symbiodinolide is a polyol macrolide isolated from the marine dinoflagellate Symbiodinium sp. in 2007. The C14-C24 fragment of symbiodinolide possessing the 17R/18R/21R absolute configuration, which was obtained as one of the degraded products of symbiodinolide, was synthesized stereoselectively fro
The degradation product C14ÀC23 2 was obtained using ethenolysis with the 2nd-generation Hoveyda-Grubbs catalyst from 62-membered lactone in symbiodinolide (1). The absolute configurations of three chiral centers in fragment 2 were assigned as 17R, 18R, and 21R by a combination of J-based configurat