Stereocontrolled Synthesis of 2,3-Anhydro-β- d -lyxofuranosyl Glycosides
✍ Scribed by Gadikota, Rajendrakumar Reddy; Callam, Christopher S.; Lowary, Todd L.
- Book ID
- 126791720
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 61 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1523-7060
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📜 SIMILAR VOLUMES
Eingegangen am 22. August 1975 Oxiranringoffnung von 9-(2,3-Anhydro-P-~-ribofuranosyl)adenin (1) mit Chlor-bzw. Bromwasserstoff gibt 3'-Chlor-bzw. 3'-Brom-3'-desoxy-xylo-adenosin (2 bzw. 4). Die entsprechende 3'-Jodverbindung 6 wird aus 1 durch Einwirkung von Natriumjodid in Gegenwart von Bortrifluo
## Abstract Methyl and phenyl β‐D‐lyxofuranoside (3a and 3b) are prepared by reaction of __5__‐__O__‐acetyl‐2,3‐__O__‐ethylboranediyl‐α‐D‐lyxofuranosyl bromide (1) with sodium methoxide and sodium phenoxide to give the protected glycosides 2a, b followed by deboronation and deacetylation. The prote