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ChemInform Abstract: Novel Glycosidation Method Using 2,6-Anhydro-2-thio Sugars for Stereocontrolled Synthesis of 2,6-Dideoxy-α- and -β- glycosides.

✍ Scribed by K. TOSHIMA; S. MUKAIYAMA; Y. NOZAKI; H. INOKUCHI; M. NAKATA; K. TATSUTA

Book ID: 112021403
Publisher: John Wiley and Sons
Year: 2010
Weight: 38 KB
Volume: 26
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199517202

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## Summarv: A novel and efficient synthesis of 2,6-dideoxy-a-glycosides was developed by use of phenyl 2,6-anhydro-1,2-dithio-D-altropyranosides as glycosyl donors in a highly stereocontrolled glycosyla tion . Highly stereocontrolled synthesis of 2,6-dideoxy glycosides is of considerable interest

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Highly β-stereoselective glycosylation by use of 1-O-acetyl-2,6-anhydro-2-thio glycosyl donor for synthesis of 2,6-dideoxy-β-glycosides

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## Gycosy1ation.r of lhe I-O-aceryl-2,6-anhydro3-thio sugar 3 with alcohols in the presence of several Lewis acids in CH2Cl2 proceeded smoothly to give the corresponding &Cl-glycosides with high srereocontrol in high yields. and the selectivity of the gIycosylaLon was highly independent on Lewis a

ChemInform Abstract: Synthesis of 4-Subs

ChemInform Abstract: Synthesis of 4-Substituted-2-acetamido-2,4-dideoxy-mannopyranoses Using 1,6-Anhydro Sugar Chemistry.

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ChemInform Abstract: Synthesis and NMR S

ChemInform Abstract: Synthesis and NMR Spectra of 1,6-Anhydro-2,3-dideoxy-2,3-epimino- and 1,6-Anhydro-3,4-dideoxy-3,4-epimino-β-D-hexopyranoses.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v