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Stereocontrolled Solid-Phase Synthesis of Oligonucleoside H-Phosphonates by an Oxazaphospholidine Approach

✍ Scribed by Naoki Iwamoto; Natsuhisa Oka; Terutoshi Sato; Takeshi Wada

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
654 KB
Volume
121
Category
Article
ISSN
0044-8249

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## Abstract The ZnCl~2~‐mediated glycosidation of an α‐1,2‐epoxide, prepared by epoxidation of a glycal with 3,3‐dimethyldioxirane, with an incoming glycal acceptor is not __a priori__, as advocated by __Danishefski et al__, a stereospecific process.