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Stereocontrolled palladium-catalysed umpolung allylation of aldehydes with allyl acetates

โœ Scribed by Monika Vogt; Sascha Ceylan; Andreas Kirschning


Book ID
108283322
Publisher
Elsevier Science
Year
2010
Tongue
French
Weight
943 KB
Volume
66
Category
Article
ISSN
0040-4020

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Allyl acetates were synthesised from allenes utilising methodology based on the general reactivity of p-allyl palladium intermediates which participate efficiently in transformations involving nucleophiles. Reactions of allenes and aryl iodides in the presence of AcONa and Pd(OAc) 2 /PPh 3 as the c