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Stereochimie du cyclohexano-2,3 bicyclo (3,3,1) nonanol-2 one-9 et des cyclohex̀ano-2, 3 bicyclo (3,3,1) nonanediols-2, 9.

✍ Scribed by MM.Jean Mounet; Jean Huet; Jacques Dreux


Book ID
104249687
Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
175 KB
Volume
9
Category
Article
ISSN
0040-4039

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✦ Synopsis


La cCtolisation interne du dioxo-2,2'

dicyclohexylme'thane (I) conduit 5 un cvclo-


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The title compound has been synthesized stereoselectively based on a new methodology for the construction of erythro-1,3-diols. Endo-1,3-dimethyl-2,9-dioxabicyclo[3.3.1]nonane (11, first isolated by Heemann and Francke in 1976 from Norway spruce attacked by the ambrosia beetle (Tgypodendron Lineatum