Bicyclo[3.3.1]nonane-2,9-dione derivatives
โ Scribed by E. N. Aredova; V. V. Sevost'yanova; M. M. Krayushkin; S. S. Novikov; N. F. Karpenko
- Book ID
- 112439811
- Publisher
- Springer
- Year
- 1976
- Tongue
- English
- Weight
- 274 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
3-Azabicyclo[3.3.1]nonane-2,4-dione (cyclohexane-1,3-dicarboximide, C 8 H 11 NO 2 ) forms a 1:1 solvate with acetic acid (C 2 H 4 O 2 ). The crystal structure comprises hydrogen-bonded chains containing alternating cyclohexane-1,3-dicarboximide and acetic acid molecules.
The title compound has been synthesized stereoselectively based on a new methodology for the construction of erythro-1,3-diols. Endo-1,3-dimethyl-2,9-dioxabicyclo[3.3.1]nonane (11, first isolated by Heemann and Francke in 1976 from Norway spruce attacked by the ambrosia beetle (Tgypodendron Lineatum