A polycrystalline sample of a new polymorph of the title compound, C~8~H~11~NO~2~, was produced during a variable-temperature X-ray powder diffraction study. The crystal structure was solved at 1.67 Å resolution by simulated annealing from laboratory powder data collected at 250 K. Subsequent Rietve
3-Azabicyclo[3.3.1]nonane-2,4-dione–acetic acid (1/1)
✍ Scribed by Hulme, Ashley T. ;Johnston, Andrea ;Florence, Alastair J. ;Tocher, Derek A.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 278 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
3-Azabicyclo[3.3.1]nonane-2,4-dione (cyclohexane-1,3-dicarboximide, C 8 H 11 NO 2 ) forms a 1:1 solvate with acetic acid (C 2 H 4 O 2 ). The crystal structure comprises hydrogen-bonded chains containing alternating cyclohexane-1,3-dicarboximide and acetic acid molecules.
📜 SIMILAR VOLUMES
## VII R =CH,C,HS COOH Ber. dtsch. chem. Ges. 65, 792 (1932) . l a ) A. Bkitu und R. R6/3Zer, Ber. dtsch. chem. Ges. 72, 265 (1939).
**Facile synthesis of derivatives of 2,4‐diphenyl‐3‐azabicyclo[3.3.1]nonane and 7,9‐diphenyl‐8‐azabicyclo[4.3.1]decane** The facile synthesis of hydantoins, cyanhydrins and aminonitriles derived from 2,4‐diphenyl‐3‐azabicyclo[3.3.1]nonanone and 7,9‐diphenyl‐8‐azabicyclo[4.3.1]decanone is described.