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Bicyclo(3,3,1) Nonane-2,9-diones

✍ Scribed by J.R. Hargreaves; P.W. Hickmott


Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
203 KB
Volume
7
Category
Article
ISSN
0040-4039

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A polycrystalline sample of a new polymorph of the title compound, C~8~H~11~NO~2~, was produced during a variable-temperature X-ray powder diffraction study. The crystal structure was solved at 1.67 Å resolution by simulated annealing from laboratory powder data collected at 250 K. Subsequent Rietve

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The title compound has been synthesized stereoselectively based on a new methodology for the construction of erythro-1,3-diols. Endo-1,3-dimethyl-2,9-dioxabicyclo[3.3.1]nonane (11, first isolated by Heemann and Francke in 1976 from Norway spruce attacked by the ambrosia beetle (Tgypodendron Lineatum