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Stereochemistry of the transition state in Diels-Alder reactions

✍ Scribed by B. S. Él'yanov; S. K. Shakhova; B. D. Polkovnikov; L. A. Rar


Book ID
112443789
Publisher
Springer
Year
1979
Tongue
English
Weight
146 KB
Volume
28
Category
Article
ISSN
1573-9171

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The stereochemistry of diels-alder react
✍ Yitzhak Apeloig; Dorit Arad; Moshe Kapon; Mercedes Wallerstein 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 302 KB

The stereochemistry of the Diels-Alder reactions of 3 cyclopropenes was determined unequivocally by X-ray and NOE studies. Tetrachlorocyclopropene yields exo-adducts with (r)-l-R-1,3-butadiene (R=OCH3, OCOCH3, OSiMe ), with 1,4\_diphenylbutadieKand with furan. 1,2-bromochlorocyclopropene yields with