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Stereochemistry of the photochemical Diels-Alder reaction

✍ Scribed by Seeley, Douglas A.


Book ID
126223092
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
310 KB
Volume
94
Category
Article
ISSN
0002-7863

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The stereochemistry of diels-alder react
✍ Yitzhak Apeloig; Dorit Arad; Moshe Kapon; Mercedes Wallerstein πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 302 KB

The stereochemistry of the Diels-Alder reactions of 3 cyclopropenes was determined unequivocally by X-ray and NOE studies. Tetrachlorocyclopropene yields exo-adducts with (r)-l-R-1,3-butadiene (R=OCH3, OCOCH3, OSiMe ), with 1,4\_diphenylbutadieKand with furan. 1,2-bromochlorocyclopropene yields with