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Integrity of alkene stereochemistry in the Diels—Alder reaction

✍ Scribed by Joseph B. Lambert; Charles D. McLaughlin; Victor Mark


Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
229 KB
Volume
32
Category
Article
ISSN
0040-4020

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The stereochemistry of diels-alder react
✍ Yitzhak Apeloig; Dorit Arad; Moshe Kapon; Mercedes Wallerstein 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 302 KB

The stereochemistry of the Diels-Alder reactions of 3 cyclopropenes was determined unequivocally by X-ray and NOE studies. Tetrachlorocyclopropene yields exo-adducts with (r)-l-R-1,3-butadiene (R=OCH3, OCOCH3, OSiMe ), with 1,4\_diphenylbutadieKand with furan. 1,2-bromochlorocyclopropene yields with