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Correlation diagrams and the mechanism and stereochemistry of the photochemical Diels-Alder reaction

โœ Scribed by Epiotis, Nicolaos D.; Yates, R. L.


Book ID
127069703
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
396 KB
Volume
39
Category
Article
ISSN
0022-3263

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The stereochemistry of diels-alder react
โœ Yitzhak Apeloig; Dorit Arad; Moshe Kapon; Mercedes Wallerstein ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 302 KB

The stereochemistry of the Diels-Alder reactions of 3 cyclopropenes was determined unequivocally by X-ray and NOE studies. Tetrachlorocyclopropene yields exo-adducts with (r)-l-R-1,3-butadiene (R=OCH3, OCOCH3, OSiMe ), with 1,4\_diphenylbutadieKand with furan. 1,2-bromochlorocyclopropene yields with