𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stereochemistry of the silylcarbinol to silyl ether rearrangement

✍ Scribed by Biernbaum, Michael S.; Mosher, Harry S.


Book ID
127048646
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
416 KB
Volume
93
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Dyotropic Rearrangement of (Silyl)methyl
✍ Dr. Manfred T. Reetz; Dipl.-Ing. Miroslav Kliment; Michael Plachky πŸ“‚ Article πŸ“… 1974 πŸ› John Wiley and Sons 🌐 English βš– 241 KB πŸ‘ 2 views

On the basis of analytical data and the following arguments the new complex is assigned the structure ( 3 ) in which two tetracarbonylmanganese fragments are symmetrically bridged by two ethoxycarbonylcarbyne ligdnds. I ) In the 'H-NMR spectrum (60 MHz; 33Β°C) the methylene protons appear as a quarte

A novel rearrangement leading to methoxy
✍ Hans-Ulrich Reissig πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 221 KB

Methyl 2-siloxycyclopropanecarboxylates rearrange smocthly and quantitatively to the corresponding silyl enol ethers (2) by addition of a catalytical amount of lodo trimethylsilane. Scope and limitation of this novel process as well as the synthesis of the electron rich diene (lea\_) are described.