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Catalytic version of epoxy silyl ether rearrangements

โœ Scribed by Keisuke Suzuki; Mayumi Miyazawa; Gen-ichi Tsuchihashi

Book ID
104227752
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
242 KB
Volume
28
Category
Article
ISSN
0040-4039

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On the basis of analytical data and the following arguments the new complex is assigned the structure ( 3 ) in which two tetracarbonylmanganese fragments are symmetrically bridged by two ethoxycarbonylcarbyne ligdnds. I ) In the 'H-NMR spectrum (60 MHz; 33ยฐC) the methylene protons appear as a quarte