Acyclic a,@-dihydroxysilanes (prepared from c@-epoxysilanes) react with KH to give silyl enol ethers; the predominant stereochemistry is consistent with anti elimination via d-oxidosilanes. We have recently shown that c&p-epoxysilanes can serve as stereospecific vinyl cation equivalents in the synth
✦ LIBER ✦
Pyrolytic rearrangements of α,β-epoxysilanes to silyl enol ethers
✍ Scribed by Paul F. Hudrlik; Chung-Nan Wan; Gregory P. Withers
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 323 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
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