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Stereochemistry of the nickel(0) catalyzed reaction of bicyclo[1.1.0]butane and electron-deficient olepins

✍ Scribed by R. Noyori; H. Kawauchi; H. Takaya

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
191 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis

Bicyclo[l.l.O]butanes upon interaction with nickel(O) catalysts undergo the intramolecular retro-carbene addition to produce reactive allylcarbene-nickel(O) intermediates, which in turn cycloadd intermolecularly, in a formal sense, across an electron-poor carbon-carbon double bond giving the cyclopropane adducts. 2 With 1,2-disubstituted olefins such as dimethyl maleate and fumarate, fairly

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