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The reaction of bicyclo/1,1,0/butane with organoboranes

โœ Scribed by B.A. Kazansky; Yu.N. Bubnov; S.V. Zotova; N.M. Abramova; V.G. Kiselev; B.M. Mikhailov


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
278 KB
Volume
15
Category
Article
ISSN
0040-4039

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Bicyclo[l.l.O]butanes upon interaction with nickel(O) catalysts undergo the intramolecular retro-carbene addition to produce reactive allylcarbene-nickel(O) intermediates, which in turn cycloadd intermolecularly, in a formal sense, across an electron-poor carbon-carbon double bond giving the cyclopr

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Scheme 1. Highly strained non-classical compounds bicyclo[1.1.0]butane (A) and tricyclo[2.1.0.0 2,5 ]pentane (B) and bridgehead 1,3-(C) and bridging 2,4-dianions (D) of A.