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Stereochemistry of the Diels-Alder reaction of butadiene with cyclopropene

✍ Scribed by Baldwin, John E.; Reddy, V. Prakash


Book ID
120294982
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
497 KB
Volume
54
Category
Article
ISSN
0022-3263

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The stereochemistry of diels-alder react
✍ Yitzhak Apeloig; Dorit Arad; Moshe Kapon; Mercedes Wallerstein πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 302 KB

The stereochemistry of the Diels-Alder reactions of 3 cyclopropenes was determined unequivocally by X-ray and NOE studies. Tetrachlorocyclopropene yields exo-adducts with (r)-l-R-1,3-butadiene (R=OCH3, OCOCH3, OSiMe ), with 1,4\_diphenylbutadieKand with furan. 1,2-bromochlorocyclopropene yields with