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Stereochemistry of some “mixed hydride” reductions of 1-phenylcyclopentene oxide

✍ Scribed by Peter T. Lansbury; V.A. Pattison

Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
146 KB
Volume
7
Category
Article
ISSN
0040-4039

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✦ Synopsis

Mixed hydride" reducing agents prepared from lithium aluminum hydride (l&i) and aluminum chloride in diethyl ether have been utilized by Eliel and coworkers (l-3) for the reduction of unsymmetrical epoxides, such as styrene oxide (1) and triphenylethylene oxide (2). Depending upon the ratios of

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✍ Marc Chérest; Hugh Felkin; Nicole Prudent 📂 Article 📅 1968 🏛 Elsevier Science 🌐 French ⚖ 381 KB

The reactions of hydrides and Grignard reagents with simple open-chain alaehydes aa ketones I (L, M, S, and R being groups containing carbon and hy- drogen only) are known to lead predominantly to the diastereoisomers IIA, as predicted by "Cram's rule" (1). I ## IIA IIB According to current theo