𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Stereochemistry of reduction and methylation of 5-(trimethylsilyl)adamantan-2-one and 5-(trimethylstannyl)adamantan-2-one

✍ Scribed by Xie, Mei; Le Noble, W. J.


Book ID
120287866
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
531 KB
Volume
54
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


2-(Adamantan-1-yl)-5-methylΒ­benzoΒ­[d][1,
✍ Crane, Jonathan D ;Rogerson, Eleanor πŸ“‚ Article πŸ“… 2004 πŸ› International Union of Crystallography 🌐 English βš– 290 KB

At 150 K, the benzo [d][1,3]oxazin-4-one heterocycle in the title compound, C 19 H 21 NO 2 , lies on a crystallographic mirror plane. This group is planar despite the resulting unfavourable steric interaction between the proximal 5-methyl and 4carbonyl groups.

Definitive identification of the C-5 and
✍ S. Srivastava; C. K. Cheung; W. J. Le Noble πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 English βš– 385 KB

The E and 2-5-deutenoadamant-2-ols have been synthesized by an unambiguous route. The =C NMR spectra show the familiar 1 : 1 : 1 splitting of one of the C-5 or C-7 signals, thus allowing a definite assignment of the &atoms to be made. This assignment is in accord with the conclusion of Duddeck and I