𝔖 Bobbio Scriptorium
✦   LIBER   ✦

2-(Adamantan-1-yl)-5-methyl­benzo­[d][1,3]­oxazin-4-one

✍ Scribed by Crane, Jonathan D ;Rogerson, Eleanor

Book ID
104481737
Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
290 KB
Volume
60
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

At 150 K, the benzo [d][1,3]oxazin-4-one heterocycle in the title compound, C 19 H 21 NO 2 , lies on a crystallographic mirror plane. This group is planar despite the resulting unfavourable steric interaction between the proximal 5-methyl and 4carbonyl groups.

📜 SIMILAR VOLUMES

5-(4-Methyl­benzo­yl)-4-(4-methyl­phen­y
5-(4-Methyl­benzo­yl)-4-(4-methyl­phen­yl)-1-[(1-phenyl­ethyl­idene)amino]pyrimidin-2(1H)-one
✍ Yıldırım, Sema Öztürk ;Akkurt, Mehmet ;Önal, Zülbiye ;Büyükgüngör, Orhan 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 145 KB

Molecules of the title compound, C 27 H 23 N 3 O 2 , contain four rings that are not coplanar and the pyrimidine ring is slightly distorted from planarity. The dihedral angles between pairs of benzene rings are 88.6 (1), 88.6 (1) and 62.9 (1) . The three benzene rings form dihedral angles of 55.3 (1

1-(4-Bromo­benzo­yl)-3-(5-trifluoro­meth
1-(4-Bromo­benzo­yl)-3-(5-trifluoro­methyl-1,3,4-thia­diazol-2-yl)urea
✍ Gong, Yin-Xiang ;Yang, Xiao-Hong 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 244 KB

Single-crystal X-ray study T = 292 K Mean (C-C) = 0.004 A Disorder in main residue R factor = 0.043 wR factor = 0.115 Data-to-parameter ratio = 14.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

2,6-Bis(4-amino­phen­yl)benzo[1,2-d:5,4-
2,6-Bis(4-amino­phen­yl)benzo[1,2-d:5,4-d′]dioxazole 1-methyl­pyrrolidin-2-one trisolvate
✍ Zhao, Hui ;Sun, Li-Ping ;Ng, Seik Weng 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 137 KB

The title compound, C 20 H 14 N 4 O 2 Á3C 5 H 9 NO, crystallizes with three molecules of 1-methyl-2-pyrrolidinone. The amino groups at each end of the fused-ring heterocycle each interact with two of the solvent molecules.