✦ LIBER ✦

Definitive identification of the C-5 and C-7 NMR signals of adamantan-2-ol

✍ Scribed by S. Srivastava; C. K. Cheung; W. J. Le Noble

Publisher: John Wiley and Sons
Year: 1985
Tongue: English
Weight: 385 KB
Volume: 23
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260230404

No coin nor oath required. For personal study only.

✦ Synopsis

The E and 2-5-deutenoadamant-2-ols have been synthesized by an unambiguous route. The =C NMR spectra show the familiar 1 : 1 : 1 splitting of one of the C-5 or C-7 signals, thus allowing a definite assignment of the &atoms to be made. This assignment is in accord with the conclusion of Duddeck and Islam. Revised assignments are offered for the reported configurations of the 5-bromo-and -chloro-adamantan-2-ols, and several unusual remote deuterium isotope shifts are reported.

📜 SIMILAR VOLUMES

2H and 13C NMR spectra of deuterated ada

2H and 13C NMR spectra of deuterated adamantan-2-ols

✍ Helmut Duddeck; Md. Rabiul Islam 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 156 KB

Definitive assignment of the 13C NMR sig

Definitive assignment of the 13C NMR signals of the indole C-3 and C-3a carbons of the ajmaline, picraline and sarpagine alkaloids

✍ M. S. Morales-Ríos; P. Joseph-Nathan 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 English ⚖ 212 KB

Comparison of a 'H coupled natural abundance "C NMR spectrum of l-oxo-1,2,3,4-tetrahydrocarbazole with a single-frequency experiment in which the hydrogens three bonds away from C-3 (indole numbering) were irradiated allowed the unambiguous distinction of the C-3 and C-3a signals. The results can be

2-Polyfluoroalkylchromones. Part 12. Nit

2-Polyfluoroalkylchromones. Part 12. Nitration of 5,7-Dimethyl-2-polyhaloalkylchromones and Complete Assignment of Signals in the 1H and 13C NMR Spectra of 5,7-Dimethyl-2-trifluoromethylchromone and Its Mono- and Dinitro Derivatives.

✍ V. Ya. Sosnovskikh; B. I. Usachev; M. I. Kodess 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 98 KB 👁 1 views

## Abstract For Abstract see ChemInform Abstract in Full Text.

Two-dimensional 1H and 13C-NMR spectra o

Two-dimensional 1H and 13C-NMR spectra of 5-(2-dimethylaminoethoxy)-7-oxo-7H-benzo[c]fluorene, its precursor and metabolite

✍ Antonin Lyčka; Josef Jirman; Milan Nobilis; Eva Kvasničková; Ivo M. Hais 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 266 KB

DFT–GIAO–NBO and 13C NMR study of the δ-

DFT–GIAO–NBO and 13C NMR study of the δ-syn-axial effect in 2,4-disubstituted adamantanes

✍ B. Mikhova; B. Stamboliyska; A. Koch; H. Duddeck; E. Kleinpeter 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB

## Abstract Six groups of diastereomeric 2,4‐disubstituted adamantanes were studied with DFT–GIAO–NBO (natural orbital analysis) methods. The calculated ^13^C chemical shifts reproduce well the experimental data. It was found that among all diastereomers, those bearing substituents in δ‐__syn__‐axi

Complete Signal Assignment of the 13C-NM

Complete Signal Assignment of the 13C-NMR Spectra and Structure Determination of Corrinoids by 2D-INADEQUATE and 2D 13C, 1H-NMR Chemical Shift Correlation Using nJ(C,H)

✍ Dr. Reinhard Benn; Dr. Richard Mynott 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 345 KB 👁 2 views