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Stereochemistry of intermediates in the syntheses of dendrobium alkaloids

โœ Scribed by Masaaki Suzuki; Yoshihiro Hayakawa; Kozo Aoki; Hiroshi Nagase; Hitoshi Nakamura; Kiyoyuki Yamada; Yoshimasa Hirata


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
238 KB
Volume
14
Category
Article
ISSN
0040-4039

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The stereochemistry of intermediates in
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In the preceding papers (l), we reported that a-7-keto-decahydroquinoline was synthesized by the method of Grob (2) and derived to I in a similar way for synthesis of dl-aspldospermine(V) (3,4). The structure of the compound(I) was proved to be Ia, whose n.m.r. spectrum was well similar to that of o