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Aziridines as intermediates in diversity-oriented syntheses of alkaloids

โœ Scribed by Alexander M. Taylor; Stuart L. Schreiber

Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
735 KB
Volume
50
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The efficient synthesis of small molecules that collectively comprise optimal small-molecule screening collections is an important goal. With this in mind, we have used N-alkyl aziridines in a regio- and stereochemically controlled synthesis of polycyclic heterocycles based on nucleophilic ring opening and subsequent intramolecular cyclization.

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Bicyclic aziridines as intermediates in the photolysis of polycyclic aromatic azides.
โœ Jean Rigaudy; Christian Igier; Jacques Barcelo ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 217 KB

According to the subsequent treatment, azepines 16, x, 19 or 1,2-dihydro derivatives 18 and 20 are obtained in the phctolysis in basic med%n of Bqnthracenic azides 7b and 7c<nd przide strong evidence for the intermedlate formation of bicyclic aziridinec -